Professur Brennstoffzellen

Projekte

SE2A (DFG)

    Lennart Kösters darf sich hier über eine 3-jährige Förderung freuen und bearbeitet das Thema: "Data-driven understanding of aviation PEM fuel cells under reliability aspects". (ca. 250.000 €)

EFACA (EU)

    Wir sind Teil eines großen Konsortiums und freuen uns auf die Zusammenarbeit. Unser Schwerpunkt wird die experimentelle Umsetzung einer Phasenwechselkühlung sowie mehrerer simulativer Projekte sein.  (ca. 456.000 €)

Innovation Lehre (Land Niedersachsen)

    Unsere Gruppe konnte eine 50.000 € Förderung für die Konzeptionierung eines "hydrogen escape rooms" einwerben. 

Aktuelles

In this winter semester, we will join our forces with Electrical Engineering and teach a course on "Electrochemical storages embedded in Onboard power systems"... and of course "fuel cell systems", both in English and for bachelor (Fak. 5) or master students (Fak. 4), respectively!

Publikationen

Tagesaktuell auf Google Scholar

A 45.     Michael Heere*, Angelina Gigante, Anna-Lena Hansen, Martin Etter, Romain Moury, Jan Peter Embs, Tatsiana Burankova, Arndt Remhof, Hans Hagemann; 11B isotope containing solid-state electrolyte based on Na4B12H12B10H10; International Journal of Hydrogen Energy, submitted, 2023

A 44.     Felix Haimerl, Sunil Kumar, Michael Heere and Aliaksandr S. Bandarenka, Electrochemical Impedance Spectroscopy of PEM Fuel Cells at Low Hydrogen Partial Pressures. Efficient Cell Tests for Mass Production; Industrial Chemistry & Materials (RSC), submitted, 2023

A 43.      Till Lennart Kösters, Min Li, Arne Graf von Schweinitz, Hendrik Schefer, Regine Mallwitz, Michael Heere^*, Jens Friedrichs, Xin Gao; Experimental Study and Simulations of Hydrogen Cooling Effectiveness for Aviation PEM Fuel Cells, Scientific Reports (Nature), submitted, 2023

X 42.      German Patent Application: Michael Heere, Christian XXX, Linus XXX, Jens-Dietrich XXX, “Detection of Hydrogen XXX”, XXX / TU BS, 2023

A 41.     Hyunchul Oh, Nikolay Tumanov, Voraksmy Ban, Xiao Li, Bo Richter, Matthew Hudson, Craig Brown, Gail Iles, Luke Daemen, Dirk Wallacher, Rafael Balderas-Xicohtencatl, Anibal Ramirez-Cuesta, Yongqiang Cheng, Michael Heere, Michael Hirscher, Torben Jensen, Yaroslav Filinchuk; Ultra-dense hydrogen in small pore hydridic framework (accepted), Nature Chemistry, 2023

A 40.       Maus, Oliver; Agne, Matthias; Fuchs, Till; Till, Paul; Wankmiller, Björn; Hansen, Michael Ryan; Heere, Michael; Jalarvo, Niina; Zeier, Wolfgang, On the discrepancy between local and average structure in the fast Na+ ionic conductor Na2.9Sb0.9W0.1S4; Journal of the American Chemical Society, 2023, DOI: 10.1021/jacs.2c11803

A 39.       Alexander Skripov; Olga Babanova; Roman Skoryunov; Alexei Soloninin; Igor Golub; Michael Heere; Yaroslav Filinchuk, Dynamical properties of the magnesium borohydride – ethylenediamine compound Mg(en)1.2(BH4)2: A nuclear magnetic resonance study. Solid State Ionics, 2023. 397: p. 116232. DOI: 10.1016/j.ssi.2023.116232

A 38.       Golub, I.E., M. Heere*, V. Gounaris, X. Li, T. Steenhaut, J. Wang, H.-W. Li, I. Dovgaliuk, K. Ikeda, G. Hautier, and Y. Filinchuk, Structural insight into the magnesium borohydride – ethylenediamine solid-state Mg-ion electrolyte system. Dalton Transactions, 2023. 52(8): p. 2404-2411. DOI: 10.1039/d2dt03567g

A 37.       Jiangong Zhu, Peiji Su, Mariyam Susana Dewi Darma, Weibo Hua, Liuda Mereacre, Xinyang Liu-Théato, Michael Heere, Daniel R. Sørensen, Haifeng Dai, Xuezhe Wei, Michael Knapp, Helmut Ehrenberg; Multiscale investigation of discharge rate dependence of capacity fade for lithium-ion battery, Journal of Power Sources, 2022, 536, p. 231516, DOI: 10.1016/j.jpowsour.2022.231516.

A 36.       Risskov Sørensen, D., A. Østergaard Drejer, M. Heere, A. Senyshyn, M. Frontzek, T. Hansen, C. Didier, V.K. Peterson, D. Bomholdt Ravnsbæk, and M. Ry Vogel Jørgensen, An Easy-to-Use Custom-Built Cell for Neutron Powder Diffraction Studies of Rechargeable Batteries. Chemistry–Methods, 2022. 2(10): p. e202200046. DOI: 10.1002/cmtd.202200046

A 35.     Li, Xiao; Dovgaliuk, Iurii; Vander Donckt, Mathieu; Chernyshov, Dmitry; Heere, Michael; Frontzek, Matthias; Kimber, Simon; Li, Hai-Wen; Filinchuk, Yaroslav. Guest Rearrangement and Thermodynamics from Gas Adsorption Crystallography (submitted). Chemistry of Materials. 2022

R 34.      Erika Michela Dematteis, Mads B. Amdisen, Tom Autrey, Mark E. Bowden, Craig Buckley, Young Whan Cho, Martin Dornheim, Petra de Jongh, Jakob B. Grinderslev, Valerio Gulino, Michael Heere, Tae Wook Heo, Terry Humphries, Torben R. Jensen, Shin Young Kang, Young-Su Lee, Hai-Wen Li, Sichi Li, Kasper T. Møller, Peter Ngene, Mark Paskevicius, Marek Polanski, Liwen Wan, Brandon Wood, Michael Hirscher, Marcello Baricco; Hydrogen storage in complex hydrides: past activities and new trends. 2022 Prog. Energy 4 03200, DOI: 10.1088/2516-1083/ac7499

A 33.     Sørensen, D.R., Heere, M., Smith, A., Schwab, C., Sigel, F., Jørgensen, M.R.V., Baran, V., Schökel, A., Knapp, M., Ehrenberg, H., Senyshyn, A., Methods—Spatially Resolved Diffraction Study of the Uniformity of a Li-Ion Pouch Cell. J. Electrochem. Soc. 169, 030518, 2022, DOI: 10.1149/1945-7111/ac59f9

R 32.      Grinderslev, J.B., M.B. Amdisen, L.N. Skov, K.T. Møller, L.G. Kristensen, M. Polanski, M. Heere, and T.R. Jensen, New Perspectives of Functional Metal Borohydrides. Journal of Alloys and Compounds, 2021: p. 163014. DOI: 10.1016/j.jallcom.2021.163014

A 31.      Jiangong Zhu, Yuan Huang, Michael Knapp, Xinhua Liu, Yixiu Wang, R. Bhushan Gopaluni, Yankai Cao, Michael Heere, Martin J. Mühlbauer, Liuda Mereacre, Haifeng Dai, Xuezhe Wei, Helmut Ehrenberg; Data-driven capacity estimation of commercial lithium-ion batteries from voltage relaxation. Nat Commun 13, 2261, 2022, DOI: 10.1038/s41467-022-29837-w

A 30.      Yartys, V.A., V.V. Berezovets, P. Vajeeston, L.G. Akselrud, V. Antonov, V. Fedotov, S. Klenner, R. Pöttgen, D. Chernyshov, M. Heere, A. Senyshyn, R.V. Denys, and L. Havela, Hydrogen induced structural phase transformation in ScNiSn-based intermetallic hydride characterized by experimental and computational studies. Acta Materialia, 2023. 244: p. 118549. DOI: 10.1016/j.actamat.2022.118549

R 29.     Cuevas, F., Amdisen, M.B., Baricco, M., Buckley, C.E., Cho, Y.W., de Jongh, P., de Kort, L.M., Grinderslev, J.B., Gulino, V., Hauback, B.C., Heere, M., Humphries, T., Jensen, T.R., Kim, S., Kisu, K., Lee, Y.-S., Li, H.-W., Mohtadi, R., Møller, K.T., Ngene, P., Noréus, D., Orimo, S., Paskevicius, M., Polanski, M., Sartori, S., Skov, L.N., Sørby, M.H., Wood, B.C., Yartys, V.A., Zhu, M., Latroche, M., 2022. Metallic and complex hydride-based electrochemical storage of energy. Prog. Energy 4, 032001. DOI: 10.1088/2516-1083/ac665b

A 28.      Darma, M.S.D., J. Zhu, P. Yan, C. Zheng, M.J. Mühlbauer, D.R. Sørensen, S. Indris, T. Bergfeldt, C. Das, M. Heere, L. Mereacre, U. Geckle, A. Senyshyn, H. Ehrenberg, and M. Knapp, Managing Life Span of High-Energy LiNi0.88Co0.11Al0.01O2|C–Si Li-Ion Batteries. ACS Applied Energy Materials, 2021. 4(9): p. 9982-10002. DOI: 10.1021/acsaem.1c01946

A 27.      Gigante, A., S. Payandeh, J.B. Grinderslev, M. Heere, J.P. Embs, T.R. Jensen, T. Burankova, A. Remhof, and H. Hagemann, Structural and dynamic studies of Pr(11BH4)3. International Journal of Hydrogen Energy, 2021. 46(63): p. 32126-32134. DOI: 10.1016/j.ijhydene.2021.06.232

A 26.      Zhu, J., M. Knapp, D.R. Sørensen, M. Heere, M.S.D. Darma, M. Müller, L. Mereacre, H. Dai, A. Senyshyn, X. Wei, and H. Ehrenberg, Investigation of capacity fade for 18650-type lithium-ion batteries cycled in different state of charge (SoC) ranges. Journal of Power Sources, 2021. 489: p. 229422. DOI: 10.1016/j.jpowsour.2020.229422

A 25.      Møller, K. T., Sargent, A.-L., Remhof, A. & Heere, M*. Beyond Hydrogen Storage—Metal Hydrides as Multifunctional Materials for Energy Storage and Conversion. Inorganics 8, 58 (2020). DOI:10.3390/inorganics8110058

A 24.      Sørensen, D.R.; Drejer, A.Ø.; Karlsen, M.A.; Nielsen, U.G.; Heere, M.; Senyshyn, A.; Ravnsbæk, D.B. Effect of Oxygen Defects on the Structural Evolution of LiVPO4F1–yOy Cathode Materials. ACS Applied Energy Materials 2020, 3, 9750-9759, DOI:10.1021/acsaem.0c01348.

R 23.      Bannenberg, L.J.; Heere, M.; Benzidi, H.; Montero, J.; Dematteis, E.M.; Suwarno; Jaroń, T.; Winny, M.; Orłowski, P.A., et al. Metal (boro)hydrides for high energy density storage and relevant emerging technologies. Int. J. Hydrogen Energy 2020. DOI:10.1016/j.ijhydene.2020.08.119

A 22.      Hua, W.; Schwarz, B.; Azmi, R.; Müller, M.; Dewi Darma, M.S.; Knapp, M.; Senyshyn, A.; Heere, M.; Missiul, A.; Simonelli, L., et al. Lithium-ion (de)intercalation mechanism in core-shell layered Li(Ni,Co,Mn)O2 cathode materials. Nano Energy 2020, 105231, DOI:10.1016/j.nanoen.2020.105231.

A 21.      Sørensen, D.R.; Heere, M.*; Zhu, J.; Darma, M.S.D.; Zimnik, S.M.; Mühlbauer, M.J.; Mereacre, L.; Baran, V.; Senyshyn, A.; Knapp, M., et al. Fatigue in High-Energy Commercial Li Batteries while Cycling at Standard Conditions: An In Situ Neutron Powder Diffraction Study. ACS Applied Energy Materials 2020, 3, 6611-6622, DOI:10.1021/acsaem.0c00779.

A 20.      Heere, M.*, A.-L. Hansen, S. Payandeh, N. Aslan, G. Gizer, M.H. Sørby, B.C. Hauback, C. Pistidda, M. Dornheim, and W. Lohstroh, Dynamics of porous and amorphous magnesium borohydride to understand solid state Mg-ion-conductors. Scientific Reports 10, 9080, DOI:10.1038/s41598-020-65857-6 (2020)

P 19.      El Kharbachi, A.; Dematteis, E.M.; Shinzato, K.; Stevenson, S.C.; Bannenberg, L.J.; Heere, M.; Zlotea, C.; Szilágyi, P.Á.; Bonnet, J.P.; Grochala, W., et al. Metal Hydrides and Related Materials. Energy Carriers for Novel Hydrogen and Electrochemical Storage. The Journal of Physical Chemistry C 2020, 124, 7599-7607, DOI:10.1021/acs.jpcc.0c01806.

R 18.      Hadjixenophontos, E., E.M. Dematteis, N. Berti, A.R. Wołczyk, P. Huen, M. Brighi, T.T. Le, A. Santoru, S.P. GharibDoust, F. Peru, A.H. Dao, Y. Liu, and M. Heere*, A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity. Inorganics, 2020. 8(3): p. 17. DOI:10.3390/inorganics8030017

R 17.      Lohstroh, W. and M. Heere, Structure and Dynamics of Borohydrides Studied by Neutron Scattering Techniques: A Review. Journal of the Physical Society of Japan, 2020. 89: p. 1-12. DOI:10.7566/JPSJ.89.051011

A 16.      Zhu, J., M.S. Dewi Darma, M. Knapp, D.R. Sørensen, M. Heere, Q. Fang, X. Wang, H. Dai, L. Mereacre, A. Senyshyn, X. Wei, and H. Ehrenberg, Investigation of lithium-ion battery degradation mechanisms by combining differential voltage analysis and alternating current impedance. Journal of Power Sources, 2020. 448: p. 227575. DOI:10.1016/j.jpowsour.2019.227575

A 15.      Vidal Laveda, J., J.E. Low, F. Pagani, E. Stilp, S. Dilger, V. Baran, M. Heere, and C. Battaglia, Stabilizing Capacity Retention in NMC811/Graphite Full Cells via TMSPi Electrolyte Additives. ACS Applied Energy Materials, 2019. 2(10): p. 7036-7044. DOI:10.1021/acsaem.9b00727

R 14.      Jacques Huot, Fermín Cuevas, Stefano Deledda, Kaveh Edalati, Yaroslav Filinchuk, Thierry Grosdidier, Bjørn C. Hauback, M. Heere, Torben R.      Jensen, Michel Latroche and Sabrina Sartori, Mechanochemistry of metal hydrides: recent advances; Materials, 2019. 12(17): p. 2778. DOI:10.3390/ma12172778

A 13.      Santoru, A., C. Pistidda, M. Brighi, M.R. Chierotti, M. Heere, F. Karimi, H. Cao, G. Capurso, A.-L. Chaudhary, G. Gizer, S. Garroni, M.H. Sørby, B.C. Hauback, R. Černý, T. Klassen, and M. Dornheim, Insights into the Rb–Mg–N–H System: an Ordered Mixed Amide/Imide Phase and a Disordered Amide/Hydride Solid Solution. Inorganic Chemistry, 2018. 57(6): p. 3197-3205. DOI:10.1021/acs.inorgchem.7b03232

A 12.      Payandeh GharibDoust, S., M. Heere, C. Nervi, M.H. Sorby, B.C. Hauback, and T.R. Jensen, Synthesis, structure, and polymorphic transitions of praseodymium(iii) and neodymium(iii) borohydride, Pr(BH4)3 and Nd(BH4)3. Dalton Transactions, 2018. 47(25): p. 8307-8319. DOI:10.1039/c8dt00118a

A 11.      Liu, Y., M. Heere, L. Contreras Vasquez, C. Paterakis, M.H. Sørby, B.C. Hauback, and D. Book, Dehydrogenation and rehydrogenation of a 0.62LiBH4-0.38NaBH4 mixture with nano-sized Ni. International Journal of Hydrogen Energy, 2018. 43(34): p. 16782-16792. DOI:10.1016/j.ijhydene.2018.04.211

A 10.      Heere, M.*, O. Zavorotynska, S. Deledda, M.H. Sørby, D. Book, T. Steriotis, and B.C. Hauback, Effect of additives, ball milling and isotopic exchange in porous magnesium borohydride. RSC Advances, 2018. 8(49): p. 27645-27653. DOI:10.1039/c8ra05146a

A 9.        Heere, M.*, M.J. Mühlbauer, A. Schökel, M. Knapp, H. Ehrenberg, and A. Senyshyn, Energy research with neutrons (ErwiN) and installation of a fast neutron powder diffraction option at the MLZ, Germany. Journal of Applied Crystallography, 2018. 51(3). DOI:10.1107/S1600576718004223

A 8.        Paterakis, C., S. Guo, M. Heere, Y. Liu, L.F. Contreras, M.H. Sørby, B.C. Hauback, D. Reed, and D. Book, Study of the NaBH4–NaBr system and the behaviour of its low temperature phase transition. International Journal of Hydrogen Energy, 2017. 42(35): p. 22538-22543. DOI:10.1016/j.ijhydene.2017.03.045

A 7.        Heere, M., S.P. GharibDoust, M.H. Sørby, C. Frommen, T.R. Jensen, and B.C. Hauback, In situ investigations of bimetallic potassium erbium borohydride. International Journal of Hydrogen Energy, 2017. 42(35): p. 22468-22474. DOI:10.1016/j.ijhydene.2017.04.271

A 6.        Heere, M., S. GharibDoust, M. Brighi, C. Frommen, M. Sørby, R. Černý, T. Jensen, and B. Hauback, Hydrogen Sorption in Erbium Borohydride Composite Mixtures with LiBH4 and/or LiH. Inorganics, 2017. 5(2): p. 31. DOI:10.3390/inorganics5020031

R 5.         Frommen, C., M. Sørby, M. Heere, T. Humphries, J. Olsen, and B. Hauback, Rare Earth Borohydrides—Crystal Structures and Thermal Properties. Energies, 2017. 10(12): p. 2115. DOI:10.3390/en10122115

A 4.        Heere, M., M.H. Sørby, C. Pistidda, M. Dornheim, and B.C. Hauback, Milling time effect of Reactive Hydride Composites of NaF NaH MgB2 investigated by in situ powder diffraction. International Journal of Hydrogen Energy, 2016. 41(30): p. 13101-13108. DOI:10.1016/j.ijhydene.2016.05.153

A 3.        Heere, M., S.H.P. GharibDoust, C. Frommen, T.D. Humphries, M.B. Ley, M.H. Sørby, T.R. Jensen, and B.C. Hauback, The influence of LiH on the rehydrogenation behavior of halide free rare earth (RE) borohydrides (RE= Pr, Er). Physical Chemistry Chemical Physics, 2016. 18(35): p. 24387-24395. DOI:10.1039/c6cp04523e

A 2.        GharibDoust, S.H.P., M. Heere, M.H. Sørby, M.B. Ley, D.B. Ravnsbæk, B.C. Hauback, R. Černý, and T.R. Jensen, Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydrides. Dalton Transactions, 2016. 45(47): p. 19002-19011. DOI:10.1039/c6dt03671f

P 1.         Frommen, C., M. Heere, M.D. Riktor, M.H. Sørby, and B.C. Hauback, Hydrogen storage properties of rare earth (RE) borohydrides (RE= La, Er) in composite mixtures with LiBH4 and LiH. Journal of Alloys and Compounds, 2015. 645, Supplement 1: p. S155-S159. DOI:10.1016/j.jallcom.2015.01.113

(A - Article; R - Review; P - Proceedings; X – Patent; *corresponding author)