Veröffentlichungen

Veröffentlichungen

Miscellaneous

Patents

2024

  1. T. Li, D. Wang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    “Uranium versus Thorium: A Case Study on a Base-Free Terminal Uranium Imido Metallocene”
    Inorg. Chem. 2024, 63, 9487-9510.
    (invited article to the special issue on “Ligand-Metal Complementary in Rare Earth and Actinide Chemistry”)

  2. T. Li, Y. Heng, D. Wang, G. Zi, W. Ding, M. D. Walter,
    “Reactivity Studies on the Lewis Base-Supported Terminal Uranium Imido Metallocene [η5-1,3-(Me3C)2C5H3]2U═N(p-tolyl)(dmap)”
    Organometallics 2024, 43, 21-39.

  3. A. Ashuiev, F. Allouche, Md. A. Islam, J. P. Carvalho, K. J. Sanders, M. P. Conley, D. Klose, G. Lapadula, M. Wörle, D. Baabe, M. D. Walter, A. J. Pell, C. Copéret, G. Jeschke, G. Pintacuda, R. A. Andersen,
    “Geometry and Electronic Structure of Yb(III)[CH(SiMe3)2]3 from EPR and solid-state NMR augmented by Computations”
    Phys. Chem. Chem. Phys. 2024, 26, 8734-8746.

  4. Y. Heng, T. Li, D. Wang, G. Zi, M. D. Walter,
    “Investigating the reactivity of a Lewis base supported terminal uranium imido metallocene”
    Inorg. Chem. Front. 2024, 11, 1862-1881.

  5. S. Wang, D. Wang, Y. Hi, T. Li, W. Ding, G. Zi, M. D. Walter,
    ”Synthesis and Structure of [η5-1,2,4-(Me3Si)3C5H2]2Th(bipy) and Its Reactivity toward Small Molecules“
    Inorg. Chem. 2024, 63, 7473-7492.
  6. S. Dinauer, R. Szlosek, M. Piesch, G. Balazs, S. Reichl, L. Prock, C. Riesinger, M. D. Walter, M. Scheer,
    “Homo- and Heterobimetallic Transition Metal Cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – Unprecedented Structural Motifs of the resulting Polypnictogen Ligands”
    Dalton Trans. 2024, 53, 10201-10207.
  7. D. Wang, Y. Heng, T. Liu, G. Zi, M. D. Walter,
    “Intrinsic Reactivity of [h5-1,3-(Me3C)2C5H3]2Th(bipy) toward Small Molecules”
    Organometallics 2024, 43, in press.

 

 

2023

  1. Y. Heng, T. Li, D. Wang, F. Hou, G. Zi, M. D. Walter,
    “Synthesis and Reactivity of the Uranium Bipyridyl Metallocene [η5-1,3-(Me3C)2C5H3]2U(bipy)”
    Organometallics 2023, 42, 91-113.
  2. T. Li, D. Wang, Y. Heng, G. Hou, G. Zi, M. D. Walter,
    “Influence of the 1,2,4-Tri-tert-butylcyclopentadienyl Ligand on the Reactivity of the Uranium Bipyridyl Metallocene [η5-1,2,4-(Me3C)3C5H2]2U(bipy)”
    Organometallics 2023, 42, 392-406.

  3. T. Li, D. Wong, Y. Heng, G. Hou, G. Zi, W. Ding, M. D. Walter,
    “A Comprehensive Study Concerning the Synthesis, Structure, and Reactivity of Terminal Uranium Oxido, Sulfido, and Selenido Metallocenes”
    J. Am. Chem. Soc. 2023, 145, 14839-14855.

  4. T. Li, D. Wang, Y. Heng, G. Hou, G. Zi, M. D. Walter,
    “Reactivity of a Lewis base-supported uranium terminal imido metallocene towards small molecules”
    Dalton Trans. 2023, 52, 13618-13630.

  5. T. Li, D. Wang, Y. Heng, G. Hou, G. Zi, W. Ding, L. Maron, M. D. Walter,
    “Experimental and Computational Studies on Uranium Diazomethanediide Complexes”
    Angew. Chem. Int. Ed. Engl. 2023, 62, e202313010.

2022

  1. K. Münster, J. Raeder, M. D. Walter,
    “Synthesis and Characterisation of an Enantiomerically Pure Scandium Pentadienyl Complex and its Application in the Polymerisation of rac-Lactide”
    Dalton Trans. 2022, 51, 986-997.
  2. J. Raeder, J. H. Jördens, M. D. Walter,
    “Open Samarocene and Ytterbocenes and their Adducts with N-Heterocyclic Carbene (NHC) and Imidazolin-2-thiones”
    Austr. J. Chem. 2022, 75, 636-648.
  3. S. Wang, Y. Heng, T. Li, G. Zi, M. D. Walter,
    “Small-Molecule Activation Mediated by [η5-1,3-(Me3Si)2C5H3]2U(bipy)”
    Inorg. Chem. 2022, 61, 6234-6251.
  4. S. Wang, D. Wang, T. Li, Y. Heng, G. Hou, G. Zi, M. D. Walter,
    “Synthesis, Structure, and Reactivity of the Uranium Bipyridyl Complex [{η5-1,2,4-(Me3Si)3C5H2}2U(bipy)]”
    Organometallics 2022, 41, 1543-1557.
  5. S. Wang, Y. Heng, T. Li, D. Wang, G. Hou, G. Zi, M. D. Walter,
    “Intrinsic reactivity of [η5-1,3-(Me3Si)2C5H3]2U(η4-C4Ph2) in small molecule activation”
    Dalton Trans. 2022, 51, 11072-11085.
  6. A. Enachi, K. Münster, D. Baabe, J. Raeder, M. Freytag, P. G. Jones, W. P. Kretschmer, M. D. Walter,
    “Cationic Ni(II) Species and Their Application in Olefin Polymerizations”
    Organometallics 2022, 41, 3419-3425.

  7. K. Münster, D. Baabe, B. Kintzel, M. Böhme, W. Plass, M. D. Walter,
    “Low-Coordinate Iron(II) Amido Half-Sandwich Complexes with Large Internal Magnetic Hyperfine Fields”
    Inorg. Chem. 2022, 61, 18883-18898.

2021

  1. D. Wang, G. Hou, G. Zi, M. D. Walter,
    “Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (η5-​C5Me5)​2U(=P-​2,​4,​6-​iPr3C6H2)​(OPPh3)”
    Organometallics 2021, 40, 383-396.

  2. W. Lukens, C. H. Booth, M. D. Walter,
    “Experimental evaluation of the stabilization of the COT orbitals by 4f orbitals in COT2Ce using a Hubbard model”
    Dalton Trans. 2021, 50, 2530-2535.

  3. D. Wang, W. Ding, G. Hou, G. Zi, M. D. Walter,
    “Uranium versus Thorium: Synthesis and Reactivity of [(η5-1,2,4-(Me3C)3C5H2]U[η2-C2Ph2)”
    Chem. Eur. J. 2021, 27, 6767-6782.
  4. N. Ehrlich, M. Freytag, J. Raeder, P. G. Jones, M. D. Walter,
    “Pyrrole-based pincer ligands containing iminophosphorane moieties and their coordination chemistry with group 1 metals and magnesium”
    Z. Anorg. Allg. Chem. 2021, 647, 1462-1470.
    (invited article to the special issue on "Pincer Ligands")
  5. A. C. Fecker, M. Freytag, M. D. Walter, P. G. Jones,
    “Crystal structure of potassium triethylhydridoborate (`superhydride´)”
    Acta Cryst. E 2021, E77, 592-595.
  6. D. Wang, S. Wang, T. Li, G. Hou, G. Zi, M. D. Walter,
    “Reactivity studies involving a Lewis base supported terminal uranium phosphinidene metallocene [η5-1,3-(Me3C)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPMe3)”
    Dalton Trans. 2021, 50, 8349-8363.

  7. S. Wang, T. Li, Y. Heng, G. Hou, G. Zi, M. D. Walter,
    “Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U(═P-2,4,6-iPr3C6H2)(OPPh3)”
    Organometallics 2021, 40, 2149-2165.

  8. S. Wang, Y. Heng, T. Li, G. Hou, G. Zi, M. D. Walter,
    “Synthesis and reactivity of the uranium phosphinidene metallocene [η5-1,3-(Me3Si)2C5H3]2U(P-2,4,6-iPr3C6H2)(OPMe3): influence of the coordinated Lewis base”
    Dalton Trans. 2021, 50, 12502-12516.

2020

  1. P. Šot, M. A. Newton, D. Baabe, M. D. Walter, A. P. van Bavel, A. D. Horton, C. Copéret, J. A. van Bokhoven,
    “Non-oxidative methane coupling over silica versus silica-supported iron(II) single sites”
    Chem. Eur. J. 2020, 26, 8012-8016.

  2. M. Reiners, D. Baabe, K. Münster, M.-K. Zaretzke, M. Freytag, P. G. Jones, Y. Coppel, S. Bontemps, I. del Rosal, L. Maron, M. D. Walter,
    “NH3 formation from N2 and H2 mediated by molecular tri-iron complexes”
    Nat. Chem. 2020, 12, 740-746.

  3. A. Enachi, M. Freytag, J. Raeder, P. G. Jones, M. D. Walter,
    “Ligand Exchange Reactions of [(tmeda)NiR2] (R = CH2CMe3, CH2SiMe3, CH2CMe2Ph) with N-Heterocyclic Carbenes and Bidentate Phosphines”
    Organometallics 2020, 39, 2470-2478.

  4. D. Wang, S. Wang, G. Hou, G. Zi, M. D. Walter,
    “A Lewis Base Supported Terminal Uranium Phosphinidene Metallocene”
    Inorg. Chem. 2020, 59, 14549-14563.

  5. D. Wang, G. Hou, G. Zi, M. D. Walter,
    “(η5-​C5Me5)​2U(=P-​2,​4,​6-​iPr3C6H2)​(OPMe3) Revisited-​Its Intrinsic Reactivity toward Small Organic Molecules”
    Organometallics 2020, 39, 4085-4101.

  6. D. Wang, W. Ding, G. Hou, G. Zi, M. D. Walter,
    “Experimental and Computational Studies on a Base-​Free Terminal Uranium Phosphinidene Metallocene”
    Chem. – Eur. J. 2020, 26, 16888-16899.

  7. K. Münster, A. C. Fecker, J. Raeder, M. Freytag, P. G. Jones, M. D. Walter,
    “Enantiomerically Pure Constrained Geometry Complexes of the Rare-​Earth Metals Featuring a Dianionic N-​Donor Functionalized Pentadienyl Ligand: Synthesis and Characterisation”
    Chem. – Eur. J. 2020, 26, 16098-16110.

2019

  1. Zhang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "An Alkali Metal Halide Bridged Actinide Phosphinidiide Complex"
    Inorg. Chem. 2019, 58, 1571-1590.
  2. C. Zhang, G. Hou, G. Zi, M. D. Walter,
    "A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic molecules"
    Dalton Trans. 2019, 48, 2377-2387.
  3. C. Zhang, Y. Wang, G. Hou, W. Ding, G. Zi, M. D. Walter,
    "Experimental and computational studies on a three-membered diphosphido thorium metallaheterocycle [η5-1,3-(Me3C)2C5H3]2Th[η2-P2(2,4,6-iPr3C6H2)2]"
    Dalton Trans. 2019, 48, 6921-6930.
  4. A. C. Fecker, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and molecular structure of enantiomerically pure pentadienyl complexes of the rare-earth metals"
    Dalton Trans. 2019, 48, 8297-8302.
  5. Y. Wang, C. Zhang, G. Zi, W. Ding, M. D. Walter,
    "Preparation of a potassium chloride bridged thorium phosphinidiide complex and its reactivity towards small organic molecules"
    New J. Chem. 2019, 43, 9527-9539.
  6. M. D. Walter, R. A. Andersen,
    "Bis(fulvalene)dimetal complexes revisited: Synthesis and properties of [M2(2,2’,4,4’-(Me3C)4C10H4)2] (M = Mg, Fe, Mn)"
    Organometallics 2019, 38, 3680-3687.
  7. A. C. Fecker, K. Münster, M. Freytag, P. G. Jones, M. D. Walter,
    "Enantiomerically Pure Pentadienyl Rhodium(I) and Iridium(I) Complexes – Their Synthesis and Reactivity"
    Eur. J. Inorg. Chem. 2019, 3954-3961.
  8. L. Leemans, M. D. Walter, F. Hollmann, A. Schallmey, L. M. van Langen,
    "Multi-Catalytic Route for the Synthesis of (S)-Tembamide"
    Catalysts 2019, 9, 822.
  9. M. Reiners, A. C. Fecker, D. Baabe, M. Freytag, P. G. Jones, M. D. Walter,
    "Cobalt and nickel compounds with pentadienyl and edge-bridged pentadienyl ligands – revisited"
    Organometallics 2019, 38, 4329-4340.
  10. M. Peters, D. Baabe, M. Maekawa, D. Bockfeld, M.-K. Zaretzke, M. Tamm, M. D. Walter,
    "Pogo-Stick Iron and Cobalt Complexes: Synthesis, Structures and Magnetic Properties"
    Inorg. Chem. 2019, 58, 16475-16486.

2018

  1. N. Ehrlich, D. Baabe, M. Freytag, P. G. Jones, M. D. Walter,
    "Pyrrolyl-based Pincer Complexes of Iron - Synthesis and electronic structure"
    Polyhedron 2018, 143, 83-93.
    (invited article to the special issue on "Pincer ligands and their application")
  2. M. Reiners, M. Maekawa, D. Baabe, M.-K. Zaretzke, P. Schweyen, C. G. Daniliuc, M. Freytag, J. Raeder, J. Hohenberger, J. Sutter, K. Meyer, M. D. Walter,
    "Monomeric Fe(III) half-sandwich complexes [Cp'FeX2] - synthesis, properties and electronic structure"
    Dalton Trans. 2018, 47, 10517-10526.
    (invited article to the themed issue "New Talent: Europe")
  3. J. Raeder, M. Reiners, R. Baumgarten, K. Münster, D. Baabe, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and molecular structure of pentadienyl complexes of the rare-earth metals"
    Dalton Trans. 2018, 47, 14469-14482.
  4. C. Zhang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "A Base-Free Terminal Actinide Phosphinidene Metallocene: Synthesis, Reactivity and Computational Studies"
    J. Am. Chem. Soc. 2018, 140, 14511-14525.
  5. A. Enachi, D. Baabe, M.-K. Zaretzke, P. Schweyen, M. Freytag, J. Raeder, M. D. Walter,
    "[(NHC)CoR2]: Pre-catalysts for homogeneous olefin and alkyne hydrogenation"
    Chem. Commun. 2018, 54, 13798-13801.

2017

  1. M. Reiners, D. Baabe, P. Schweyen, M. Freytag, P. G. Jones, M. D. Walter,
    "Teaching ferrocenium how to relax - A systematic study on spin-lattice relaxation processes in tert-butyl-substituted ferrocenium derivatives"
    Eur. J. Inorg. Chem. 2017, 388-400.
    (invited article to the Cluster Issue "The Multifaceted Chemistry of Ferrocene")
  2. L. Zhang, B. Fang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "Experimental and Computational Studies on a Uranium Metallacyclocumulene"
    Organometallics 2017, 36, 898-910.
  3. L. Zhang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "Preparation of a uranium metallacyclocumulene and its reactivity towards unsaturated organic molecules"
    Dalton Trans. 2017, 46, 3716-3728.
  4. L. Zhang, C. Zhang, G. Hou, G. Zi, M. D. Walter,
    "Small Molecule Activation Mediated by a Uranium Bipyridyl Metallocene"
    Organometallics 2017, 36, 1179-1187.
  5. M. Reiners, M. Maekawa, C. G. Daniliuc, M. Freytag, P. G. Jones, P. S. White, J. Hohenberger, J. Sutter, K. Meyer, L. Maron, M. D. Walter,
    "Reactivity Studies on [Cp'Fe(μ-I)]2: Nitrido-, Sulfido- and Diselenide Iron Complexes Derived from Pseudohalide Activation"
    Chem. Sci. 2017, 8, 4108-4122.
  6. M. Reiners, D. Baabe, M.-K. Zaretzke, M. Freytag, M. D. Walter,
    "Reversible Dinitrogen Binding to [Cp'Fe(NHC)] Associated with an N2-induced Spin State Change"
    Chem. Commun. 2017, 53, 53, 7274-7277.
    (invited article to the special issue on "Emerging Investigators Issue 2017")
  7. C. Zhang, P. Yang, E. Zhou, X. Deng, G. Zi, M. D. Walter,
    "Reactivity of a Lewis Base Supported Thorium Terminal Imido Metallocene towards Small Organic Molecules"
    Organometallis 2017, 36, 4525-4538.
    (invited article to the special issue on "Organometallic Actinide and Lanthanide Chemistry")
  8. M. F. Delley, G. Lapadula, F. Nunez-Zarur, A. Comas-Vives, V. Kalendra, G. Jeschke, D. Baabe, M. D. Walter, A. J. Rossini, A. Lesage, L. Emsley, O. Maury, C. Copéret,
    "Local Structures and Heterogeneity of Silica-Supported M(III) Sites Evidenced by EPR, IR, NMR and Luminescence Spectroscopies"
    J. Am. Chem. Soc. 2017, 139, 8855-8867.
  9. N. Ehrlich, M. Kreye, D. Baabe, P. Schweyen, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and electronic ground state properties of pyrrolyl-based iron pincer complexes ― revisited"
    Inorg. Chem. 2017, 56, 56, 8415-8422.
  10. M. D. Walter, P. T. Matsunaga, C. J. Burns, L. Maron, R. A. Andersen,
    "Synthesis and Reactions of [Cp*2Yb]2(μ-Me) and [Cp*2Yb]2(μ-Me)(Me) and Related Yb2(II, III) and Yb2(III, III) Compounds"
    Organometallics 2017, 36, 4564-4578.
    (invited article to the special issue on "Organometallic Actinide and Lanthanide Chemistry")

2016

  1. M. Reiners, D. Baabe, K. Harms, M. Maekawa, C. G. Daniliuc, M. Freytag, P. G. Jones, M. D. Walter,
    "N-Heterocyclic carbene adducts to [Cp'FeI]2: Synthesis and Molecular and Electronic Structure"
    Inorg. Chem. Front. 2016, 3, 250-262.
    (invited article to the themed collection "2015 Emerging Investigators by ICF")
  2. B. Fang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "Steric and Electronic Influences of Internal Alkynes on the Formation of Thorium Metallacycles: A Combined Experimental and Computational Study"
    Organometallics 2016, 35, 1384-1391.
  3. L. Zhang, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "Influence of the 5f Orbitals on the Bonding and Reactivity in Organoactinides: Experimental and Computational Studies on a Uranium Metallacyclopropene"
    J. Am. Chem. Soc. 2016, 138, 5130-5142.
  4. M. Reiners, D. Baabe, M. Freytag, P. G. Jones, M. D. Walter,
    "Closing the gap: Preparation and characterization of the first half-open and open manganocene complexes"
    Organometallics 2016, 35, 1986-1994.
  5. P. Yang, E. Zhou, B. Fang, G. Hou, G. Zi, M. D. Walter,
    "Preparation of (η5-C5Me5)2Th(bipy) and Its Reactivity toward Small Molecules"
    Organometallics 2016, 35, 2129-2139.
  6. P. Yang, E. Zhou, G. Hou, G. Zi, W. Ding, M. D. Walter,
    "Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics"
    Chem. Eur. J. 2016, 22, 13845-13849.
  7. M. D. Walter, D. Baabe, M. Freytag, P. G. Jones,
    "N-Heterocyclic Carbene (NHC) Adducts of [(C5H5)2Mn] Revisited: Nothing More, Nothing Less than High-Spin (S = 5/2) Molecules!"
    Z. Anorg. Allg. Chem. 2016, 642, 1259-1263.
    (invited article to the special issue on "NHC-stabilization of reactive units in main group and transition metal chemistry")
  8. L. Zhang, B. Fang, G. Hou, L. Ai, W. Ding, M. D. Walter, G. Zi,
    "Intrinsic reactivity of a uranium metallacyclopropene toward unsaturated organic molecules"
    Dalton Trans. 2016, 45, 16441-16452.
  9. M. D. Walter, C. J. Burns, P. T. Matsunaga, M. E. Smith, R. A. Andersen,
    "Synthesis and Physical Properties of Pentamethylmanganocen, (C5Me5)Mn(C5H5) and the Inclusion Compounds [(C5Me5)2Yb]2[(C5H5)2M] (where M = V, Cr, Fe, Co)"
    Organometallics 2016, 35, 3488-3497.

2015

  1. M. D. Walter, C. D. Sofield, R. A. Andersen,
    "Spin Equilibria and Thermodynamic Constants for (C5H4R)2Mn, R= H or Me, in Solid Solutions of Diamagnetic Diluents"
    J. Organomet. Chem. 2015, 776, 17-22.
  2. A. C. Fecker, B.-F. Crăciun, P. Schweyen, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and characterization of N-donor-functionalized enantiomerically pure pentadienyl ligands derived from (1R)-(‒)-myrtenal"
    Organometallics 2015, 34, 146-158.
  3. M. Kreye, M. Freytag, P. G. Jones, P. G. Williard, W. H. Bernskoetter, M. D. Walter,
    "Homolytic H2 cleavage by a mercury-bridged Ni(I) pincer complex [{(PNP)Ni}2{μ-Hg}]"
    Chem. Commun. 2015, 51, 2946-2949.
  4. B. Fang, G. Hou, G. Zi, D.-C. Fang, M. D. Walter,
    "A thorium metallacyclopentadiene complex: a combined experimental and computational study"
    Dalton Trans. 2015, 44, 7927-7934.
  5. B. Fang, L. Zhang, G. Hou, G. Zi, D.-C. Fang, M. D. Walter,
    "C-H bond activation induced by thorium metallacyclopropene complexes: A combined experimental and computational study"
    Chem. Sci. 2015, 6, 4897-4906.
  6. E. Zhou, W. Ren, G. Hou, G. Zi, D.-C. Fang, M. D. Walter,
    "Small Molecule Activation Mediated By A Thorium Terminal Imido Metallocene"
    Organometallics 2015, 34, 3637-3647.
  7. M. Kreye, M. Freytag, C. G. Daniliuc, P. G. Jones, M. D. Walter,
    "The Missing Link: Manganese Complexes with Sterically Demanding Pyrrolyl Ligands"
    Z. Anorg. Allg. Chem. 2015, 641, 2109-2114.
  8. A. C. Fecker, M. Freytag, P. G. Jones, N. Zhao, G. Zi, M. D. Walter,
    "Preparation of enantiomerically pure open calcocene and strontocene complexes and their application in ring opening polymerizations of rac-lactide"
    Dalton Trans. 2015, 44, 16325-16331.
  9. B. Fang, L. Zhang, G. Hou, G. Zi, D.-C. Fang, M. D. Walter,
    "Experimental and Computational Studies on an Actinide Metallacyclocumulene Complex"
    Organometallics 2015, 34, 5669-5681.

2014

  1. E. Theuergarten, T. Bannenberg, M. D. Walter, D. Holschumacher, M. Freytag, C. G. Daniliuc, P. G. Jones, M. Tamm,
    "Computational and experimental investigations on CO2 and N2O fixation by sterically demanding N-heterocyclic carbenes (NHC) and NHC/borane FLP systems"
    Dalton Trans. 2014, 43, 1651-1662.
  2. M. Reiners, A. C. Fecker, M. Freytag, P. G. Jones, M. D. Walter,
    "Pentadienyl chemistry of the heavy alkaline-earth metals revisited"
    Dalton Trans. 2014, 43, 6614-6617.
  3. N. Zhao, G. Hou, X. Deng, G. Zi, M. D. Walter,
    "Group 4 Metal Complexes with New Chiral Pincer NHC-Ligands: Synthesis, Structure, and Catalytic Activity"
    Dalton Trans. 2014, 43, 8261-8272.
  4. M. Kreye, C. G. Daniliuc, M. Freytag, P. G. Jones, M. D. Walter,
    "Coordination chemistry of sterically encumbered pyrrolyl ligands to chromium(II): Mono(pyrrolyl)chromium and diazachromocene formation"
    Dalton Trans. 2014, 43, 9052-9060.
  5. W. Ren, E. Zhou, B. Fang, G. Zi, D.-C. Fang, M. D. Walter,
    "Si-H Addition followed by C-H bond activation induced by a terminal thorium imido metallocene: A combined experimental and computational study"
    Chem. Sci. 2014, 5, 3165-3172.
  6. M. Reiners, D. Baabe, P. Schweyen, M. Freytag, P. G. Jones, M. D. Walter,
    "The coordination chemistry of 2,4-di(tert-butyl)pentadienyl revisited"
    Inorg. Chim. Acta 2014, 422, 167-180.
  7. A. C. Fecker, B. - F. Crăciun, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and coordination chemistry of pentadienyl ligands derived from (1R)-(-)myrtenal"
    Organometallics 2014, 33, 3792-3803.
  8. W. Ren, E. Zhou, B. Fang, G. Hou, G. Zi, D.-C. Fang, M. D. Walter,
    "Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imido Metallocene towards Organic Azides and Diazoalkanes"
    Angew. Chem. Int. Ed. 2014, 53, 11310-11314.
  9. H. Bauer, A. Glöckner, A. C. Tagne Kuate, S. Schäfer, Y. Sun, M. Freytag, M. Tamm, M. D. Walter, H. Sitzmann,
    "How big is a Cp? Novel cycloheptatrienyl zirconium complexes with tri-, tetra- and pentasubstituted cyclopentadienyl ligands"
    Dalton Trans. 2014, 43, 15818-15828.
  10. B. Fang, W. Ren, G. Hou, G. Zi, D.-C. Fang, L. Maron, M. D. Walter,
    "An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity and Computational Studies"
    J. Am. Chem. Soc. 2014, 136, 17249-17261.

2013

  1. M. Kreye, A. Glöckner, C. G. Daniliuc, M. Freytag, P. G. Jones, M. Tamm, M. D. Walter,
    "Sterically encumbered pyrrolyl ligands and their incorporation into the cycloheptatrienyl zirconium coordination sphere"
    Dalton Trans. 2013, 42, 2192-2200.
  2. W. Ren, W. W. Lukens, G. Zi, L. Maron, M. D. Walter,
    "Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study"
    Chem. Sci. 2013, 4, 1168-1174.
  3. A. C. Fecker, A. Glöckner, C. G. Daniliuc, M. Freytag, P. G. Jones, M. D. Walter,
    "Synthesis and coordination chemistry of an enantiomerically pure pentadienyl ligand"
    Organometallics 2013, 32, 874-884.
  4. M. D. Walter, P. S. White, M. Brookhart,
    "Synthesis, Structure and Computational Studies on a Cationic T-shaped Pd-Complex"
    New J. Chem. 2013, 37, 1128-1133.
  5. M. Maekawa, C. G. Daniliuc, P. G. Jones, J. Hohenberger, J. Sutter, K. Meyer, M. D. Walter,
    "Synthesis of [Cp'Fe(η3-BH4)] and its conversion to [Cp'Fe(BH2)]3"
    Eur. J. Inorg. Chem. 2013, 4097-4104.
    (invited article to the "Cluster Issue on Small Molecule Activation")
  6. M. Kreye, D. Baabe, P. Schweyen, M. Freytag, C. G. Daniliuc, P. G. Jones, M. D. Walter,
    "Synthesis and reactivity of sterically encumbered diazaferrocenes"
    Organometallics 2013, 32 5887-5898.
    (invited article to the special issue "Ferrocene - Beauty and Function")
  7. M. D. Walter, P. S. White, C. K. Schauer, M. Brookhart,
    "Stability and Dynamic Processes in 16VE Iridium(III) Ethyl Hydride and Rhodium(I) σ-Ethane Complexes: Experimental and Computational Studies "
    J. Am. Chem. Soc. 2013, 135 15933-15947.
  8. M. Kreye, J. W. Runyon, M. Freytag, P. G. Jones, M. D. Walter,
    "Phosphine-substituted sterically encumbered pyrrolyl ligands - Synthesis and reactivity studies"
    Dalton Trans. 2013, 42 16846-16856.
  9. D. Peng, Y. Zhang, , X. Du, L. Zhang, X. Leng, M. D. Walter, Z. Huang,
    "Phosphinite-iminopyridine iron catalysts for chemoselective alkene hydrosilylation"
    J. Am. Chem. Soc. 2013, 135, 19154-19166.

2012

  1. W. Ren, G. Zi, M. D. Walter,
    "Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand"
    Organometallics 2012, 31, 672-679.
  2. A. Glöckner, H. Bauer, M. Maekawa, T. Bannenberg, C. G. Daniliuc, P. G. Jones, Y. Sun, H. Sitzmann, M. Tamm, M. D. Walter,
    "How big is a Cp? Cylcoheptatrienyl Zirconium Complexes with Bulky Cyclopentadienyl and Indenyl Ligands"
    Dalton Trans. 2012, 41, 6614-6624.
  3. W. Ren, X. Deng, H. Song, G. Zi, M. D. Walter,
    "A bipyridyl thorium metallocene: synthesis, structure and reactivity"
    Dalton Trans. 2012, 41, 5965 - 5973.
  4. A. Glöckner, T. Bannenberg, K. Ibrom, C. G. Daniliuc, M. Freytag, P. G. Jones, M. D. Walter, M. Tamm,
    "Flexibility of an open indenyl ligand in iron(II) complexes"
    Organometallics 2012, 31, 4480-4494.
  5. M. D. Walter, P. S. White,
    "[{Cp′Fe(μ-OH)}3]: the synthesis of a unique organometallic iron hydroxide"
    Dalton Trans. 2012, 41, 8506-8508.
  6. M. Maekawa, C. G. Daniliuc, M. Freytag, P. G. Jones, M. D. Walter,
    "Complexes of Manganese, Iron and Cobalt with Sterically Demanding Indenyl Ligands"
    Dalton Trans. 2012, 41, 10317-10327.
  7. M. Maekawa, M. Römelt, C. G. Danilliuc, P. G. Jones, P. S. White, F. Neese, M. D. Walter,
    "Reactivity Studies on [Cp'MnX(thf)]2: Manganese Amide and Polyhydride Synthesis"
    Chem. Sci. 2012, 3, 2972-2979.
  8. M. D. Walter, P. S. White,
    "Reactivity Studies on [Cp'FeI]2: Monomeric Amido, Phenoxo and Alkyl Complexes"
    Inorg. Chem. 2012, 51, 11860-11872.

2011

  1. C. H. Booth, E. D. Bauer, E. D. Bŏzin, S. J. L. Billinge, M. D. Walter,
    "Pair-distribution function analysis of the structural valence transition in Cp*2Yb(4,4′-Me2-bipy)"
    J. Phys.: Conf. Ser. 2011, 273, 012149.
  2. M. D. Walter, P. S. White,
    "[Cp′FeI]2 as convenient entry into iron-modified pincer complexes: bimetallic η6,κ1-POCOP-pincer iron iridium compounds"
    New J. Chem. 2011, 35, 1842-1854.
  3. W. Ren, G. Zi, D.-C. Fang, M. D. Walter,
    "Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity and Computational Studies"
    J. Am. Chem. Soc. 2011, 133, 13183-13194.
  4. M. D. Walter, J. Grunenberg, P. S. White,
    "Reactivity Studies on [Cp'FeI]2: From Iron Hydrides to P4-Activation"
    Chem. Sci. 2011, 2, 2120-2130.
  5. W. Ren, G. Zi, D.-C. Fang, M. D. Walter,
    "A Base-Free Thorium Terminal Imido Metallocene: Synthesis, Structure and Reactivity"
    Chem. Eur. J. 2011, 17, 12669-12682.
  6. M. D. Walter, P. S. White, C. K. Schauer, M. Brookhart,
    "The Quest for Stable σ-Methane Complexes: Computational and Experimental Studies"
    New J. Chem. 2011, 35, 2884-2893.

2010

  1. M. D. Walter, M. Tamm,
    "Bond Breaking News: Tungsten Cleaves Aromatic C-C Bonds"
    Angew. Chem. Int. Ed. 2010, 49, 3264-3267. (Highlight)
  2. W. W. Lukens, M. D. Walter,
    "Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method"
    Inorg. Chem. 2010, 49, 4458-4465.
  3. C. H. Booth, D. Kazhdan, E. L. Werkema, M. D. Walter, W. W. Lukens, E. D. Bauer, Y-J. Hu, L. Maron, O. Eisenstein, M. Head-Gordon, R. A. Andersen,
    "Intermediate-Valence Tautermerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines"
    J. Am. Chem. Soc. 2010, 132, 17537-17549.

2009

  1. M. D. Walter, P. S. White, M. Brookhart,
    "γ-Agostic Interactions Stabilize the Propagating Species in the Vinyl Addition Polymerization of Norbornene"
    Chem. Comm. 2009, 6361-6363.
    (invited article, web-theme issue "Catalysis in Organic Synthesis")
  2. M. D. Walter, R. A. Moorhouse, S. A. Urbin, P. S. White, M. Brookhart,
    "γ-Agostic Species as Key Intermediates in the Vinyl Addition Polymerization of Norbornene with Cationic (allyl)Pd Catalysts: Synthesis and Mechanistic Insights"
    J. Am. Chem. Soc. 2009, 131, 9055-9069.
  3. C. H. Booth, M. D. Walter, D. Kazhdan, Y.-J. Hu, W. W. Lukens, E. D. Bauer, L. Maron, O. Eisenstein, R. A. Andersen,
    "Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-shell Singlet Formation"
    J. Am. Chem. Soc. 2009, 131, 6480-6491.
  4. M. D. Walter, R. A. Moorhouse, P. S. White, M. Brookhart,
    "Vinyl Addition Polymerization of Norbornene with Cationic (allyl)Ni Catalysts: Mechanistic Insights and Characterization of First Insertion Products"
    J. Polym. Sci. Part A: Polym. Chem. 2009, 47, 2560-2573.
  5. M. D. Walter, C. D. Sofield, C. H. Booth, R. A. Andersen,
    "Spin Equilibria in Monomeric Manganocenes: Solid State Magnetic and EXAFS Studies"
    Organometallics 2009, 28, 2005-2019.
  6. M. D. Walter, C. H. Booth, W. W. Lukens, R. A. Andersen,
    "Cerocene Revisited: The Electronic Structure of and Interconversion between Ce2(C8H8)3 and Ce(C8H8)2"
    Organometallics 2009, 28, 698-707.

2008

  1. M. D. Walter, C. D. Sofield, R. A. Andersen,
    "Preparation and Reactions of Base-Free Bis(1,3-di-tert-butylcyclopentadienyl)titanium, Cp'2Ti, and Related Compounds"
    Organometallics 2008, 27, 2959-2970.

2007

  1. M. D. Walter, D. J. Berg, R. A. Andersen,
    "Coordination of 1,4-Diazabutadiene Ligands to Decamethylytterbocene: Additional Examples of Spin Coupling in Ytterbocene Complexes"
    Organometallics 2007, 26, 2296-2307.
  2. M. D. Walter, D. Bentz, F. Weber, O. Schmitt, G. Wolmershäuser, H. Sitzmann,
    "Cation size dependent reactivity of lanthanide trihalides with bulky alkylcyclopentadienyl anions"
    New J. Chem. 2007, 31, 305-318.

2006

  1. R. Fandos, M. D. Walter, D. Kazhdan, R. A. Andersen,
    "Selective Syntheses of Homo- and Hetero-dimetal Complexes with Tetramethyltetraannulene Ligand of the Type [(TMTAA)(ML,ML')] where M and M' are Rh(I) or Ir(I) and L and L' are COD or (CO)2"
    Organometallics 2006, 25, 3678-3687.
  2. M. D. Walter, R. Fandos, R. A. Andersen,
    "Synthesis and Magnetic Properties of Cerium Macrocyclic Complexes with tmtaaH2, Tetramethyldibenzotetraaza[14]-annulene"
    New J. Chem. 2006, 30, 1065-1070.
  3. M. D. Walter, D. J. Berg, R. A. Andersen,
    "Coordination Complexes of Decamethylytterbocene with 4,4'-Disubstituted Bipyridines: An Experimental Study of Spin Coupling in Lanthanide Complexes"
    Organometallics 2006, 25, 3228-3237.
  4. M. D. Walter, F. Weber, G. Wolmershäuser, H. Sitzmann,
    "A hexanuclear ytterbium anion with fourteen azido ligands"
    Angew. Chem. Int. Ed. 2006, 45, 1903-1905.
  5. M. D. Walter, M. Schultz, R. A. Andersen,
    "Weak paramagnetism in compounds of the type Cp'2Yb(bipy)"
    New J. Chem. 2006, 30, 238-246.
  6. R. Fandos, M. D. Walter,
    "Bis(µ-pyridinyl-1-oxide)-1κO1:2κC2;1κC2:2κO1-bis[(η4-cycloocta-1,5-diene) rhodium(I)]"
    Acta Cryst. E 2006, 62, m264-m266.

2005

  1. C. H. Booth, M. D. Walter, M. Daniel, W. W. Lukens, R. A. Andersen,
    "Self-Contained Kondo Effect in Single Molecules"
    Phys. Rev. Lett. 2005, 95, 267202/1-267202/4.
  2. M. D. Walter, G. Wolmershäuser, H. Sitzmann,
    "Calcium, Strontium, Barium and Ytterbium Complexes with Cyclooctatetraenyl or Cyclononatetraenyl Ligands"
    J. Am. Chem. Soc. 2005, 127, 17494-17503.
  3. G. Zi, L. Jia, E. L. Werkema, M. D. Walter, J. P. Gottfriedsen, R. A. Andersen,
    "Preparation and Reactions of Base-Free Bis(1,2,4-tri-tert-butylcyclopentadienyl)uranium Oxide, Cp'2UO"
    Organometallics 2005, 24, 4251-4264.
  4. M. Schultz, C. D. Sofield, M. D. Walter, R. A. Andersen,
    "Coordination complexes of bivalent ansa-ytterbocenes: synthesis, structure and comparison with related unbridged ytterbocenes and ansa-ferrocenes"
    New. J. Chem. 2005, 29, 919-927.

2004

  1. C. D. Sofield, M. D. Walter, R. A. Andersen,
    "Amidobis[(η5-1,3-di(trimethylsilyl)cyclopentadienyl]titanium(III)"
    Acta Cryst C 2004, 60, m265-m466.
  2. C. D. Sofield, M. D. Walter, R. A. Andersen,
    "µ2-Oxo-di[bis(η5-1,3-di(tert-butyl)cyclopentadienyl)titanium(III)]"
    Acta Cryst E 2004, 60, m1417-m1419.
  3. C. D. Sofield, M. D. Walter, R. A. Andersen,
    "Bis[(η5-1,3-bis(trimethylsilyl)cyclopentadienyl]vanadium(II)"
    Acta Cryst E 2004, 60, m1296-m1297.

2003

  1. J. L. Krinsky, M. N. Stavis, M. D. Walter,
    "Di-µ-chloro-bis[(tetrahydrofuran-κO)(η5-1,2,4-tri-tert-butylcyclopentadienyl) manganese(II)] pentane solvate"
    Acta Cryst E 2003, 59, m497-m499.
  2. H. Sitzmann, F. Weber, M. D. Walter, G. Wolmershäuser,
    "Mono(alkylcyclopentadienyl) Complexes of Barium and Strontium"
    Organometallics 2003, 22, 1931-1936.

2002

  1. H. Sitzmann, M. D. Walter, G. Wolmershäuser,
    "Tricarbonyl(methyl)(η5-1,2,4-tricyclohexylcyclopentadienyl)-molybdenum"
    Acta Cryst E 2002, 58, m777-m778.
  2. H. Sitzmann, M. D. Walter, G. Wolmershäuser,
    "A Triple-Decker Sandwich Complex of Barium"
    Angew. Chem. Int. Ed. 2002, 41, 2315-2316.

Miscellaneous

  1. M. Tamm, M. D. Walter,
    "New Talents: Europe"
    Dalton Trans. 2014, 43, 4196-4196. (Editorial)
  2. R. C. Fischer, J. J. Weigand, I. Siewert, M. Walter, K. Ray, P. Kurz,
    "Trendberichte 2013: Anorganische Chemie"
    Nachr. Chem. 2014, 62, 219-251.
  3. S. Inoue, T. Böttcher, I. Siewert, M. D. Walter, K. Ray, P. Kurz,
    "Trendberichte 2014: Anorganische Chemie"
    Nachr. Chem. 2015, 63, 227-255.
  4. I. Siewert, M. D. Walter, U.-P. Apfel,
    "Trendberichte 2015: Koordinationschemie und Bioanorganik"
    Nachr. Chem. 2016, 64, 232-245.
  5. M. D. Walter,
    "Recent advances in transition metal-catalyzed dinitrogen activation"
    Adv. Organomet. Chem. 2016, 65, 261-377.
  6. T. Wilke, B. Bartram, S. Karrie, M. Korte, R. Köster, M. Walter, M. Wejner,
    "Teach Chemistry Forward: An Innovative Course Concept for Universities and Schools"
    New Perspectives in Science Education, Conference Proceedings 2018.
  7. M. Reiners, N. Ehrlich, M. D. Walter,
    "Synthesis of 1,3,5-tri(tert-butyl)cyclopenta-1,3-diene and its metal complexes Na{1,2,4-(Me3C)3C5H2} and Mg{η5-1,2,4-(Me3C)3C5H2}2"
    Inorg. Synth. 2018, 37, 199-204.

  8. M. D. Walter, G. Nocton,
    “Organometallic rare-earth chemistry”
    in Rare Earth Chemistry, R. Pöttgen, T. Jüstel, C. A. Strassert (Eds.), De Gruyter, 2020, 201-222.

  9. M. D. Walter,
    “Alkene, alkyne and allyl complexes of the actinides”
    Comprehensive Organometallic Chemistry IV, 2022, 3, 449-476.

  10. K. Münster, M. D. Walter,
    “Monocyclopentadienyl and other half-sandwich complexes of iron”
    Comprehensive Organometallic Chemistry IV, 2022, 7, 46-184.

  11. M. D. Walter,
    “Ammonia formation revisited“
    Nature Chem. 2022, 14, 12-13. (News & Views) 

  12. M. D. Walter,
    “Organouranium Chemistry”
    in Encyclopedia of Inorganic and Bioinorganic Chemistry, R. A. Scott (Ed.), 2023.

Patents

  1. C. Limburg, D. Löffler, H. Wilmer, M. Walter, M. Reiners,
    "Process for the generation of thin inorganic films"
    WO2017178400 (A1), 2017.
  2. C. Limburg, D. Löffler, H. Wilmer, M. Walter, M. Reiners,
    "Hapto-3-Pentadienyl Cobalt or Nickel Precursors and their Use in Thin Film Deposition Processes"
    WO2018015305 (A1), 2018.